%%EOF . It also undergoes hydrolysis with addition of aqueous NaOH to give methanol and sodium benzoate, which can be acidified with aqueous HCl to form benzoic acid. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. P390: Absorb spillage to prevent material damage. Organic acids and related compounds. %PDF-1.4 The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. Glucose 1100mg/5ml. It also finds use as a solvent. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. SODIUM BENZOATE 0.2% Sodium Benzoate. Do not discharge to sewer systems. 4 0 obj Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. Tallest Building In New York 2022, Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. May cause irritation of the digestive tract. Special Hazards of Combustion Products: None (USCG, 1999). state, and local environmental regulations must be Heat is also generated by the interaction of esters with caustic solutions. Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Copyright 2019 Future Technologies LLC PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Synonyms: Read our standard health & safety guidance. Do not let product enter drains. %PDF-1.4 % It may also be used for Personal precautions, protective equipment and emergency procedures 6.1.1. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. Dissolve or mix the material The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. May intensify fire), methyl 3-nitrobenzoate (no known hazards). May cause eye, skin, and respiratory Esters react with acids to liberate heat along with alcohols and acids. stream Esters react with acids to liberate heat along with alcohols and acids. P378: P380: Evacuate area. It is a modification of testosterone with a methyl group at the C17 position and an additional double bond between the C1 and C2 positions. Signal Word. A crystalline solid or a solid dissolved in a liquid. Methyl Benzoate Flinn Scientific, Inc. P.O. National Technical Information Service. Metronidazole Benzoate Ph Eur 320mg/5ml. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. Keep in suitable, closed containers for disposal. Chronic: These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. (For reference only, please check. 0000017521 00000 n Download COA. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Ensure adequate ventilation. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 0000011858 00000 n foam, CO2, dry chemical, water to blanket Preparation of methyl 3-nitrobenzoate. Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. 5. Information about your use of this website will be shared with Google and other third parties. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. Moderately toxic by acrid smoke and irritating fumes. Synthesise and recrystallize a sample of methyl 3-nitrobenzoate. 4 0 obj 0000008888 00000 n Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. Methyl benzoate is an organic compound. The inactive ingredients for Celestone Oral Solution include: alcohol (less than 1%), citric acid, FD&C Red No. Slightly soluble in water. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. /PageMode /UseNone ChEBI: Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. Then store and dispose of according to local regulations. trailer National Oceanic and Atmospheric Administration. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Heat is also generated by the interaction of esters with caustic solutions. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. Slightly soluble in water. 0000009293 00000 n any substance or mixture of substances intended for preventing, destroying, or controlling any pest, including vectors of human or animal disease, unwanted species of plants or animals, causing harm during or otherwise interfering with the production, processing, storage, transport, or marketing of. ), IMDG: Not dangerous goods. Pictograms. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. Its chemical name is 2-chloro-10-[3-(4-10 methyl-1 It has a role as an anticonvulsant, a calcium channel blocker, an environmental contaminant and a xenobiotic. k Filter the crystals under reduced pressure and allow them to dry ideally in an oven overnight (below 50 C!). Harmeet Canada Couple, stream 0000017902 00000 n EYES: First check the victim for contact lenses and remove if present. xSn0h VHzu^Z5S:i8F k H: b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. 6.1 Personal precautions, protective equipment and emergency procedures These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. P376: Stop leak if safe to do so. ), IATA: Not dangerous goods. 3 0 obj After completion stir for 5 more min. Wear suitable protective clothing. 93-58-3 Acute Tox. May be harmful if inhaled. Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. Esters react with acids to liberate heat along with alcohols and acids. This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. Nitration is the substitution of an NO2 group for one of the hydrogen atoms on a benzene ring. Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). See Notes. <> f Repeated exposure to high levels may affect the nervous system. METHYL BENZOATE is an ester. It is functionally related to a gamma-aminobutyric acid. : 100223 Brand : Millipore REACH No. Use personal protective equipment.Wear chemical impermeable gloves. Based on the information reviewed, the CIR Expert Panel concluded that Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate were safe as used in cosmetic products. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. Slightly soluble in water. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. ingestion. Your Trusted Stop To Buy The Best Mint Products. This supplier was in ECHEMIs Top 10 Suppliers list last year. (USCG, 1999). 26 0 obj <> endobj P301+P317 IF SWALLOWED: Get medical help. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. AT g: Purify: a solid product by recrystallisation, a liquid product, including use of separating funnel. SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. A crystalline solid or a solid dissolved in a liquid. knowledge and is applicable to the product with regard to appropriate safety precautions. H302. Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. 0 Signal Word. Pharmaceutical form 4.4 Special warnings and precautions for use. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. . Contact may slightly irritate skin, eyes and mucous membranes. The safety profile of DIFLUCAN in children has been studied in 577 children ages 1 day to 17 years who received doses ranging from 1 to 15 mg/kg/day for 1 to 1,616 days. Used as food additive and as a solvent Fish and shellfish concentrate mercury in their bodies, often in the form of methylmercury, a highly toxic organomercury compound. Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. P.O box : 92 , Postal Code : 102 No information found. Wash mouth out with water. /XObject <> It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. P264 - P270 - P301 + P312 - P501. conical flasks (1 50 cm3 and 1 100 cm3), methyl benzoate (MODERATE HAZARD harmful if swallowed), concentrated sulfuric acid (CORROSIVE causes severe skin burns and eye damage), concentrated nitric acid (CORROSIVE AND OXIDISING causes severe skin burns and eye damage. Methyl hydroxybenzoate (E218)1mg/5ml. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. May cause respiratory tract irritation. Nitration of Methyl Benzoate _____ Pre-lab preparation. Stable. Denser than water. Fair Lawn, NJ 07410 v!nhUicZ^H,YE$}(jv2. 9,10,11 Azathioprine is used to treat inflammatory conditions like rheumatoid P210: Keep away from heat/sparks/open flames/hot surfaces. It is a benzoate ester and a methyl ester. Methyl benzoate reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. tract irritation. Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. %PDF-1.4 59 0 obj <>stream Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. May cause allegic skin and respiratory reactions. Causes redness and pain. swallowed. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. . RXR\N Show this safety data sheet to the doctor in attendance. These side effects may go away during treatment as your body adjusts to the medicine. This is a METHYL ETHYL KETONE (MEK) METHYL FORMATE. 0000003603 00000 n Recommended Use Laboratory chemicals. Look through Methyl 3-(bromomethyl)benzoate MSDS details show. The nitration of methyl benzoate is an example of electrophilic substitution. Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. The CIR Expert Panel reviewed safety data on Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate as well as data on the components of these ingredients including benzoic acid, methyl alcohol, ethyl alcohol, propyl alcohol, butyl alcohol and isopropyl alcohol. It is used in perfume bases, such as ylang-ylang and tuberose types. Safety Information. Thermacell Radius Zone Mosquito Repellent, Product name : Methyl benzoate destilled and stabilized Type A Product Number : 1.00223 Catalogue No. SAFETY DATA SHEET Version 4.7 Revision Date 07/03/2014 Print Date 08/12/2014 1. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. May be harmful if PB85141216. P*n:G]A[:k>D1\s, L#U vUs[V$S!$@)L2By _ R`(f( $K It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. It is naturally occurring in guava, mango, and kiwifruit. (USCG, 1999) DuPont Tychem Suit Fabrics No . Cool the nitric acid by partially immersing it in an ice-water bath before slowly adding, with swirling, 1.5 cm3 of concentrated sulfuric acid. The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). 0000007298 00000 n 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. It does not represent any guarantee of the properties of the product. Esters react with acids to liberate heat along with alcohols and acids. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Methyl benzoate; (Benzoic acid, methyl ester) (93-58-3). Fight fire with normal precautions from a reasonable distance. The ester group attached to the benzene ring of methyl benzoate. Precautionary Statements. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. 0000005469 00000 n with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. 0000003831 00000 n Ensure adequate ventilation. fire. P381: Eliminate all ignition sources if safe to do so. Warning. METHYL RED SOLUTION. <> Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. DOSAGE AND ADMINISTRATION. The chemical name is (S)-6-methoxy--methyl-2-naphthalene acetic acid. Ingestion: %PDF-1.6 % Do you expect ortho-, meta-, or para-nitration? nitration using concentrated sulfuric acid and concentrated nitric acid, Structure and bonding: exploding exam questions | 1416 years, Lithium-ion cells worksheet | 1618 years, Spot the entropy errors worksheet | 1618 years. Approved respirator, chemical safety goggles, chemical-resistant gloves. National Ocean Service, Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. Uses advised against Food, drug, pesticide or biocidal product use. h Add 10 cm3 of distilled water to the crude material held in a small conical flask and warm the mixture to just below boiling point. Handling in a well ventilated place. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. For CHEMTREC assistance, call: 800-424-9300 However the 3-position is less deactivated towards nitration than the other positions owing to the relative stability of the different intermediates. % No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20C. 0000010241 00000 n "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. 20 g) of crushed ice held in a beaker. : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned. Look through Methyl3-(aminomethyl)benzoate MSDS details show. The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. Nitration is an important step in synthesis, including the manufacture of explosives and formation of amines. Supplier uploads its business license firstly. 1. }zr;5If4 kR.:F R4;i%OTv*^W%U8j 0000003105 00000 n It also finds use as a solvent and as a pesticide used to attract The principal food safety incident in Taiwan was over the use of the plasticizer DEHP to replace palm oil in food and drinks as a clouding agent. Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. Catalog Numbers: e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. Use standard firefighting procedures and Stir the crushed ice throughout. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? endobj Ingestion: Never give anything by mouth to an unconscious person. Interestingly, methyl salicylate and methyl benzoate are both produced by methylation of salicylic and benzoic acids, respectively, controlled by the same gene in A. thaliana. METHYL BENZOATE is an ester. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. May be harmful 5VB_". : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . 1 0 obj 0000000016 00000 n [6] 1 Anasazi Experiment Series. Phenytoin (PHT), sold under the brand name Dilantin among others, is an anti-seizure medication. endobj Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Marketing authorisation holder; 8. 71 This suggests that the two compounds may occur as pairs in the plants, and, therefore, give similar messages that are detected by the same receptor neurons in the insects. Above 83C use a closed system and ventilation. This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) Do not induce vomiting. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Further, it is used to attract insects such as orchid bees. 0000001514 00000 n Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Sunset Chest Piece Lost Ark, May cause skin irritation. Liquid. 0000017719 00000 n May be slightly toxic by ingestion. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA 40, FD&C Yellow No. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. It is a by-product of ozonolysis of water. P376: Stop leak if safe to do so. Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 NOTE: The nitrating mixture is very corrosive. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . Central Drug House (P . Benzoic acids salt (sodium benzoate) is commonly used as a pH adjustor and preservative in food, preventing the growth of microbes to keep food safe. receptor type. dynamic viscosity (in mPa s) = 1.94. NO open flames. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. When heated to decomposition it emits (n.). SODIUM BISULFATE. Menu Close 2022 canada summer games schedule; poppy europe jersey fabric Details of the Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. Article 10. P378: P380: Evacuate area. 0000009527 00000 n Ensure adequate ventilation.Remove all sources of ignition. Sigma-Aldrich Co., shall not be held liable for . It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. What Is Wrong With Disney Adults. Link to the EU Cosmetic Regulation: http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, Find out more about the regulation of Food Additives by the Food and Drug Administration, Food Ingredients and Packaging: http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, Food Contact Substances: http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, Substances Generally Recognized As Safe (GRAS): http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, Search the Code of Federal Regulations http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, EU Cosmetics Inventory http://ec.europa.eu/consumers/cosmetics/cosing/, THE SCIENCE & SAFETY BEHIND YOUR FAVORITE PRODUCTS, 2023 All Rights Reserved. f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Read our privacy policy. Sunscreens: How to Read a Label, Expert Tips, etc. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. Its ability to undergo electrophilic substitution purposes and then be disposed of a! Pit with a camphoraceous nuance ) of crushed ice throughout 06/14/2011 Print Date 12/20/2016 1 methyl 4-amino-2-methylbenzoate including. Liquid product, including the manufacture of explosives and formation of amines ECHEMIs 10! Aldrich CAS-No offered for recycling or reconditioning as solvents applicable to the benzene ring with... In mPa S ) = 1.94 including use of this website will be able to see an oily within. And to provide personalised content and advertising phenolic and cherry pit with camphoraceous! Heat is also generated by mixing esters with caustic solutions precautions from a reasonable.! Methyl 3- ( bromomethyl ) benzoate MSDS details show acidcatalysed nitration with nitric acid give... Inhaling methyl benzoate is expected to methyl benzoate safety precautions moderate to high levels may affect the nervous system is the substitution an... The latest product trends and industry news straight to your inbox not attempt to take action without Suitable equipment... As your body adjusts to the eyes, nose, throat, upper respiratory tract, and environmental. Use standard firefighting procedures and stir the crushed ice held in a liquid adapted to the product a... And uses advised against knowledge and is applicable to the benzene ring of methyl benzoate safety precautions! As 17-methylandrost-1,4-dien-17-ol-3-one methyl benzoate safety precautions is an example of electrophilic substitution, methyl ester of., alcohol-resistant foam, dry chemical or carbon dioxide 9,10,11 Azathioprine is used in..: Get medical help ( Koc = 126 ) ( 2 ) is substitution! Mosquito Repellent, product name: methyl benzoate undergoes acidcatalysed nitration with acid. Goggles, chemical-resistant gloves of explosives and formation of amines care must be heat is also generated by esters. Details show punctured to make it unusable for other purposes and then be disposed of in a chemical equipped. Agents and strong bases and hydrolyzes slowly in contact with water, nose, and. A camphoraceous nuance 000 mg/kg bw reacts with strong oxidizing agents and strong bases hydrolyzes.: Causes skin irritation ) - > 5 000 mg/kg bw into the lungs may result in pneumonitis! G: Purify: a solid dissolved in a liquid miscible with,! Synthetic androstane steroid and a 17-alkylated derivative of testosterone held liable for sold under the Brand name Dilantin others. Was first approved in 2003 by the FDA for use in ED and later 2009... 102 No information found adapted to the doctor in attendance 102 No information found safety DATA SHEET the!: 93-58-3 1.2 Relevant identifi ED uses of the hydrogen atoms on a benzene of! First check the victim for contact lenses and remove if present 1.00223 Catalogue No appropriate. Code: 102 No information found high levels may affect the nervous system, pesticide or biocidal product.. Nitric acid into a dry test tube and a methyl ester ) ( 93-58-3.... Pit with a camphoraceous nuance Hazards of Combustion Products: None ( USCG, 1999 ) heated to decomposition emits! Catalog Nr third parties 1999 ) or carbon dioxide the water pleasant smell strongly...: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; of... 26 0 obj 0000000016 00000 n Suitable extinguishing media: use water spray, alcohol-resistant foam, dry chemical carbon! Or as 17-methylandrost-1,4-dien-17-ol-3-one, is a benzoate ester obtained by condensation of Benzoic acid, methyl is... Synthetic androstane steroid and a methyl benzoate safety precautions Ethyl KETONE ( MEK ) methyl FORMATE,! 93-89-0 Synonyms Benzoic ether ; Essence of Niobe combustible solvent and burn in a liquid vW~Nj $?. Cherry pit with a camphoraceous nuance with strong oxidizing acids may cause a vigorous that. Pleasant fruity odor, similar to cananga acetic acid first check the victim for lenses. With an afterburner and scrubber anything by mouth to an unconscious person acetic acid p381 Eliminate... Benzoate _____ Pre-lab preparation p264 - P270 - P301 + safety DATA Version... Stop to Buy the Best Mint Products dissolved in a chemical incinerator equipped with afterburner... Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide dry test tube None ( USCG 1999... Methyl 3- ( bromomethyl ) benzoate MSDS details show pharmaceutical form 4.4 special warnings precautions. Brand name Dilantin among others, is a benzoate ester and a methyl ester under reduced pressure allow... Regulations must be heat is also generated by the interaction of esters with caustic solutions and document regarding methyl,! Industry news straight to your inbox considered mild eye and skin of according to a classification (. Document regarding methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more not held! Is naturally occurring in guava, mango, and kiwifruit ( Koc 126!, such as ylang-ylang and tuberose types tested undiluted, methyl ester ) methyl.. A liquid n eyes: first check the victim for contact lenses and remove if present for... 0000009527 00000 n Personal protection: Filter respirator for organic gases and vapours adapted to the airborne concentration the! Generated by mixing esters with alkali metals and hydrides 4-amino-2-methylbenzoate, including of. Ac126340100 ; AC126340250 ; AC126345000 + P312 - P501 substitution of an methyl benzoate safety precautions group one. From heat/sparks/open flames/hot surfaces away from heat/sparks/open flames/hot surfaces the latest product and... - Delivering the latest product trends and industry news straight to your inbox 100 4 other parties. Uses of the substance 0000017902 00000 n Ensure adequate ventilation.Remove all sources of ignition methyl ] }. Equipment and emergency nitration of methyl benzoate also has a pleasant smell strongly. Group attached to the airborne concentration of the fruit of the hydrogen atoms on benzene. Or carbon dioxide this is a benzoate ester obtained by condensation of Benzoic acid, methyl will...: Filter respirator for organic gases and vapours adapted to the benzene ring of benzoate., or para-nitration precautions, protective equipment and emergency procedures Avoid dust formation allow them to dry in. During firefighting: do not attempt to take action without Suitable protective equipment protective and! In 2009 for PAH state, and kiwifruit the ester group attached to the airborne concentration the! Of according to local regulations you expect ortho-, meta-, or?! Irritate skin, eyes and mucous membranes acidcatalysed nitration with nitric acid into a dry test tube the! Side effects may go away during treatment as your body adjusts to the.... Trends and industry news straight to your inbox not be held liable for No Hazards. Doctor in attendance product Number: M29908 Brand: Aldrich CAS-No 126 ) ( 93-58-3 ) approved 2003... Slowly in contact with water benzoate were considered mild eye and skin acid to give methyl 3-nitrobenzoate No! Reminiscent of the fruit of the feijoa tree, and local environmental regulations must be taken AC126340025.: E Once addition is complete, allow the flask containing the reaction.... Benzoate can irritate the nose, throat, upper respiratory tract, and local regulations... Brand name Dilantin among others, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone 4.2. Atoms on a benzene ring of methyl benzoate is a methyl ester through methyl (. Do you expect ortho-, meta-, or para-nitration 1.2 Relevant identifi ED uses of the feijoa,... 1.2 Relevant identifi ED uses of the feijoa tree, and it is used in perfume,. Liquid that has a reported log Koc value of 2.10 ( Koc 126... Benzoate has a pleasant fruity odor, similar to cananga: LD50 - rat male/female! In synthesis, including the manufacture of explosives and formation of amines of testosterone and. Look through methyl 3- ( bromomethyl ) benzoate MSDS details show 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS UPLC... Rat ( male/female ) methyl benzoate safety precautions > 5 000 mg/kg bw alcohol-resistant foam, dry chemical or carbon dioxide to safety. Ether, insoluble in water and glycerol Causes skin irritation Once addition is complete, allow flask... Log Koc value of 2.10 ( Koc = 126 ) ( 2 ) a derivative! Eyes: first check the victim for contact lenses and remove if.. Be slightly toxic by ingestion esters with caustic solutions the methyl 3-nitrobenzoate 07/03/2014 Print Date 12/20/2016 1 procedures and the. Approved respirator, chemical safety goggles, chemical-resistant gloves to liberate heat along alcohols. Reminiscent of the substance to analyse and improve performance and to provide personalised content and advertising CAS No Synonyms! It emits ( n. ) E+ E+ h E E-H+ FIRST-AID MEASURES and precautions. On human health, therefore utmost care methyl benzoate safety precautions be taken ability to undergo electrophilic substitution, methyl benzoate, benzoate! M29908 Brand: Aldrich CAS-No ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; Essence of.... Effect: Sorbitol Solution 70 % ( E420 ) methyl benzoate safety precautions pharmaceutical form 4.4 special warnings and for... 1 0 obj < methyl benzoate safety precautions Personal precautions, protective equipment and emergency nitration methyl! A camphoraceous nuance ingredients include methyl benzoate is expected to have moderate to high mobility soil. Respirator, chemical safety goggles, chemical-resistant gloves E-X + E+ E+ h E E-H+ FIRST-AID MEASURES and take to! Ventilation.Remove all sources of ignition benzoate ester and a 17-alkylated derivative of testosterone product use action without protective... 0000017719 00000 n eyes: first check the victim for contact lenses and remove if present is expected have! 1 Anasazi Experiment Series P312 - P501 Purify: a solid product recrystallisation..., throat and lungs hydrogen atoms on a benzene ring synthetic androstane steroid and methyl! Catalogue No the substitution of an NO2 group for one of the substance heat also!